Facile in situ generation of highly active (arylimido)vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization (ROMP) of cyclic olefins by immediate phenoxy ligand exchange-Reference-Cited by-同舟云学术

Facile in situ generation of highly active (arylimido)vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization (ROMP) of cyclic olefins by immediate phenoxy ligand exchange

Published:2018 Issue:96 Volume:54 Page:13559-13562
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hayashibara Hitomi¹²³,Hou Xiaohua¹²³,Nomura Kotohiro¹²³^ORCID

Affiliation:

1. Department of Chemistry, Tokyo Metropolitan University

2. Hachioji

3. Japan

Abstract

Remarkably active vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization of cyclic olefins can be generated in situ upon addition of C₆F₅OH or C₆Cl₅OH.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07974A

Reference37 articles.

1. Handbook of Metathesis , ed. R. H. Grubbs , Wiley-VCH , Weinheim, Germany , 2003

2. Olefin Metathesis: Theory and Practice , ed. K. Grela , John Wiley & Sons, Inc. , Hoboken, New Jersey, USA , 2014

3. Handbook of Metathesis , ed. R. H. Grubbs and A. G. Wenzel , Wiley-VCH , Weinheim, Germany , 2nd edn, 2015 , vol. 1

4. Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes

5. R. R. Schrock , in Alkene Metathesis in Organic Synthesis , ed. A. Fürstner , Springer , Berlin, Germany , 1998 , p. 1

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Ring-opening metathesis polymerization with vanadium(V) alkylidenes: Survey of initiators, density-functional theory calculations, and functional group tolerance;Journal of Organometallic Chemistry;2023-09

2. Reactivity of 1.1.1-Propellane with (silox)₃M (M = Ti, V, Cr): Structures of (silox)₃V═(^cC₄H₄)═CH₂ and [(silox)₃Cr–(1.1.1-C₅H₆)−]₂;Organometallics;2022-09-03

3. Metal‐Free Ring‐Opening Metathesis Polymerization with Hydrazonium Initiators**;Angewandte Chemie International Edition;2022-04-13

4. Metal‐Free Ring‐Opening Metathesis Polymerization with Hydrazonium Initiators**;Angewandte Chemie;2022-04-13

5. Attempts at generating metathesis-active Fe(IV) and Co(IV) complexes via the reactions of (silox)2M(THF)2, [(silox)3M][Na(THF)2] (M = Fe, Co), and related species with propellanes and triphenylboron;Polyhedron;2022-03