F-coordinated single-atom Ru species: efficient and durable catalysts for photo-thermal synergistic catalytic CO2 hydrogenation to methane

Author:

Tang Yunxiang1,Wang Hao1,Guo Chan1,Wang Lige2,Zhao Tingting1,Yang Zhengyi1,Xiao Shikang1,Liu Jiurong1ORCID,Jiang Yanyan1ORCID,Zhao Yufei3ORCID,Wen Xiao-Dong45ORCID,Wang Fenglong1ORCID

Affiliation:

1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan, 250061, P. R. China

2. Shenzhen Research Institute of Shandong University, Shenzhen, Guangdong, 518057, P. R. China

3. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

4. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi, 030001, P. R. China

5. National Energy Center for Coal to Liquids, Synfuels China Co., Ltd, Huairou District, Beijing, 101400, P. R. China

Abstract

We show that fine-tuning of coordination structure of Ru sites can significantly enhance performances for CO2 hydrogenation to methane under mild conditions in a photo-thermal synergistic catalytic process.

Funder

National Natural Science Foundation of China

Science, Technology and Innovation Commission of Shenzhen Municipality

University of Jinan

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

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