Visible light-enabled alkylation of enol acetates with alkylboronic acids for the synthesis of α-alkyl ketones

Author:

Li Yunpu1,Ma Zhenqiang1,Liu Xiaopei2,Li Zhongxian2,Zhao Fengqian1ORCID,Wu Junliang1ORCID

Affiliation:

1. Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, P.R. China

2. High & New Technology Research Center, Henan Academy of Sciences, Zhengzhou 450002, P.R. China

Abstract

Visible light-catalyzed alkylation of enol acetates with alkylboronic acids has been successfully developed to synthesize α-alkyl ketones. A variety of asymmetric ketones with various structural skeletons were obtained under mild conditions.

Funder

Zhengzhou University

Henan Academy of Agricultural Sciences

National Natural Science Foundation of China-Henan Joint Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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