Metal-free hydrogenation with formic acid over N-doped carbon

Author:

Xia Ziyi1,Wang Bowei1234ORCID,Li Jiayi1,Zhang Fangying5,Chen Ligong1234ORCID,Li Yang134ORCID

Affiliation:

1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China

2. Zhejiang Institute of Tianjin University, Shaoxing, P. R. China

3. Tianjin Engineering Research Center of Functional Fine Chemicals, Tianjin 300350, P. R. China

4. Guangdong Laboratory of Chemistry and Fine Chemical Industry Jieyang Center, Guangdong Province 522000, P. R. China

5. National Key Laboratory for Nuclear Fuel and Materials, Nuclear Power Institute of China, Chengdu 610213, P. R. China

Abstract

Doped nitrogen significantly increased the nitrobenzene conversion and selectivity for aniline. Graphitic nitrogen is conducive to the adsorption of nitrobenzene and basic pyridinic nitrogen has a positive effect on the activation of formic acid.

Funder

Natural Science Foundation of Tianjin City

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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