The importance of the composite mechanisms with two transition states in the F− + NH2I SN2 reaction-Reference-Cited by-同舟云学术

The importance of the composite mechanisms with two transition states in the F− + NH2I SN2 reaction

Published:2020 Issue:23 Volume:22 Page:12929-12938
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Li Yan¹²³⁴^ORCID,Li Yongfang⁵⁶⁷⁴^ORCID,Wang Dunyou¹²³⁴^ORCID

Affiliation:

1. College of Physics and Electronics

2. Shandong Normal University

3. Jinan 250014

4. China

5. Fujian Institute of Research on the Structure of Matter

6. Chinese Academy of Sciences (CAS)

7. Fuzhou 350002

Abstract

The two-transition-state mechanisms, especially the double-inversion mechanism, make the largest contribution to the S_N2 reactivity of the F⁻ + NH₂I reaction.

Funder

National Natural Science Foundation of China

Taishan Scholar Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP01942A

Reference49 articles.

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5. F− + CH3I → FCH3 + I− Reaction Dynamics. Nontraditional Atomistic Mechanisms and Formation of a Hydrogen-Bonded Complex

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