Interlocking increases the persistence of N-heterocyclic carbenes in solution-Reference-Cited by-同舟云学术

Interlocking increases the persistence of N-heterocyclic carbenes in solution

Published:2020 Issue:35 Volume:56 Page:4773-4776
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hsueh Fang-Che¹²³⁴^ORCID,Tsai Chi-You¹²³⁴^ORCID,Lai Chien-Chen⁵⁶⁴^ORCID,Liu Yi-Hung¹²³⁴^ORCID,Peng Shie-Ming¹²³⁴^ORCID,Chiu Sheng-Hsien¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. National Taiwan University

3. Taipei

4. Taiwan

5. Institute of Molecular Biology

6. National Chung Hsing University

Abstract

Encircling macrocycles around N-heterocyclic carbenes, in the form of [2]rotaxanes, is a practical approach for increasing the persistence of these highly reactive species in solution.

Funder

National Taiwan University

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01183E

Reference36 articles.

1. G. Bertrand , Carbene Chemistry: From Fleeting Intermediates to Powerful Reagents , Taylor & Francis , New York , 2002

2. Stable Carbenes

3. Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

4. A Brief Survey of Our Contribution to Stable Carbene Chemistry

5. A stable crystalline carbene

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