Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers

Author:

Delmas Luke C.12345ORCID,White Andrew J. P.12345,Pugh David2675ORCID,Evans Arwyn8375,Isbell Mark Antonin8375,Heng Jerry Y. Y.8375ORCID,Lickiss Paul D.12345ORCID,Davies Robert P.12345ORCID

Affiliation:

1. Molecular Sciences Research Hub

2. Department of Chemistry

3. Imperial College London

4. White City

5. UK

6. King's College London

7. London

8. Department of Chemical Engineering

Abstract

A new approach to the development of MOF materials with low water affinity is presented using siloxane-derived linkers. The low water affinity is conferred by the linker without the requirement of any post-synthetic processing apart from activation.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference38 articles.

1. P. Puthiaraj , Y.-R.Lee , S.Ravi , S.Zhang and W.-S.Ahn , Post-combustion Carbon Dioxide Capture Materials , The Royal Society of Chemistry , London , 2019 , pp. 153–205

2. O. M. Yaghi , M. J.Kalmutzki and C. S.Diercks , Introduction to Reticular Chemistry: Metal-Organic Frameworks and Covalent Organic Frameworks , Wiley-VCH , Weinheim , 2019

3. S. Kaskel , The chemistry of metal-organic frameworks: synthesis, characterization, and applications , Wiley-VCH , Weinheim , 2016

4. Applications of water stable metal–organic frameworks

5. Hydrophobic Metal–Organic Frameworks

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