A porphyrin(2.1.2.1) bis-boron complex as a deep-red AIE luminophore induced by intermolecular F

A porphyrin(2.1.2.1) bis-boron complex as a deep-red AIE luminophore induced by intermolecular F–π interaction

Published:2022 Issue:25 Volume:51 Page:9606-9610
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Ningchao¹,Lv Xiaojuan¹,Xiao Bentian¹,Kuzuhara Daiki²,Mei Peifeng³,Aratani Naoki³^ORCID,Yamada Hiroko³^ORCID,Qiu Fengxian¹^ORCID,Pan Jianming¹,Xue Songlin¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China

2. Faculty of Science and Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551, Japan

3. Division of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara 630-0192, Japan

Abstract

Four novel boron complexes were synthesized from saddle-shaped porphyrins(2.1.2.1) as new cyclic ligands. The saddle shape confers unique structure-dependent photophysical properties, especially in emission.

Funder

Jiangsu University

China Postdoctoral Science Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01289H

Reference48 articles.

1. BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties