SiO2 assisted Cu0–Cu+–NH2 composite interfaces for efficient CO2 electroreduction to C2+ products

Author:

Zhang Zi-Yang1,Tian Hao1,Jiao Han1,Wang Xin1,Bian Lei1,Liu Yuan1ORCID,Khaorapapong Nithima2ORCID,Yamauchi Yusuke345ORCID,Wang Zhong-Li1ORCID

Affiliation:

1. Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

2. Materials Chemistry Research Center, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand

3. Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, QLD 4072, Australia

4. Department of Materials Process Engineering, Graduate School of Engineering, Nagoya University, Nagoya, 464–8603 Japan

5. Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722 South Korea

Abstract

SiO2 assisted abundant Cu0–Cu+–NH2 composite interfaces enhance the adsorption and activation of CO2 and H2O, strengthen the adsorption of CO intermediates, and promote C–C coupling to produce C2+ products.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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