H/D exchange under mild conditions in arenes and unactivated alkanes with C6D6 and D2O using rigid, electron-rich iridium PCP pincer complexes-Reference-Cited by-同舟云学术

H/D exchange under mild conditions in arenes and unactivated alkanes with C6D6 and D2O using rigid, electron-rich iridium PCP pincer complexes

Published:2020 Issue:39 Volume:11 Page:10705-10717
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Smith Joel D.¹²³⁴^ORCID,Durrant George⁵⁶⁷⁸,Ess Daniel H.⁵⁶⁷⁸,Gelfand Benjamin S.¹²³⁴^ORCID,Piers Warren E.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Calgary

3. Calgary

4. Canada

5. Department of Chemistry and Biochemistry

6. Brigham Young University

7. Provo

8. USA

Abstract

The synthesis and characterization of an iridium polyhydride complex (Ir-H4) supported by an electron-rich PCP framework and capable of mild hydrogen/deuterium exchange catalysis is described.

Funder

Canada Research Chairs

National Science Foundation

Natural Sciences and Engineering Research Council of Canada

Institute of Infection and Immunity

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02694H

Reference65 articles.

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2. Homogeneous metal-catalyzed exchange of aromatic compounds. Isotopic hydrogen labeling procedure

3. Homogeneous platinum(II)-catalysed hydrogen exchange in the alkylbenzenes: relationship to simple alkane exchange

4. Activation of saturated hydrocarbons by metal complexes in solution

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