The role of covalency in enhancing stability of Eu and Am complexes: a DFT comparison of BTP and BTPhen-Reference-Cited by-同舟云学术

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The role of covalency in enhancing stability of Eu and Am complexes: a DFT comparison of BTP and BTPhen

Published:2023 Issue:29 Volume:25 Page:19453-19461
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Fryer-Kanssen Izaak¹,Malcomson Thomas²^ORCID,Austin Jonathan³,Kerridge Andrew¹^ORCID

Affiliation:

1. Department of Chemistry, Lancaster University, Bailrigg, Lancaster, LA1 4YB, UK

2. Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

3. National Nuclear Laboratory, Chadwick House, Birchwood Park, Warrington, WA3 6AE, UK

Abstract

BTP and BTPhen complexes of americium are shown to exhibit greater covalent bond stabilisation than their europium analogues.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP01832F

Reference85 articles.

1. New bis(triazinyl) pyridines for selective extraction of americium(iii)

2. EXTRACTION OF Am(lll) AND Eu(lll) NITRATES BY 2-6-DI-(5,6-DIPROPYL-1,2,4-TRIAZIN-3-YL)PYRIDINES 1

3. SELECTIVE EXTRACTION OF Am(III) OVER Eu(III) BY 2,6-DITRIAZOLYL- AND 2,6-DITRIAZINYLPYRIDINES1

4. Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N-Donor Ligands

5. Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions

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1. Selective Gold Precipitation by a Tertiary Diamide Driven by Thermodynamic Control;Inorganic Chemistry;2024-05-09

2. Complexation of Am(iii) and Eu(iii) with DRAPA (N,N-dialkyl-6-amide-pyridine-2-carboxylic acid);Dalton Transactions;2023

3. Tailoring the pore size of expanded porphyrinoids for lanthanide selectivity;RSC Advances;2023

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