A systematic study on the kinetics of H-shift reactions in pristine acyl peroxy radicals-Reference-Cited by-同舟云学术

A systematic study on the kinetics of H-shift reactions in pristine acyl peroxy radicals

Published:2023 Issue:41 Volume:25 Page:28205-28212
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Seal Prasenjit¹^ORCID,Barua Shawon¹,Iyer Siddharth¹^ORCID,Kumar Avinash¹^ORCID,Rissanen Matti¹²

Affiliation:

1. Aerosol Physics Laboratory, Physics Unit, Tampere University, 33720 Tampere, Finland

2. Department of Chemistry, University of Helsinki, P. O. Box 55, FI-00014, Helsinki, Finland

Abstract

A systematic study is carried out for the first time on H-shifts in pristine acyl peroxy radicals. The fastest rates were found to be in the range of 10−2 to 10−1 s−1, remaining competitive even under moderately polluted atmospheric conditions.

Funder

Academy of Finland

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP01833D

Reference18 articles.

1. Rapid Hydrogen Shift Reactions in Acyl Peroxy Radicals

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3. Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement VI. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry

4. Rapid Hydrogen Shift Scrambling in Hydroperoxy-Substituted Organic Peroxy Radicals

5. H migration in peroxy radicals under atmospheric conditions

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