Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten–iridium clusters

Author:

Simpson Peter V.1234,Randles Michael D.1234,Gupta Vivek1234,Fu Junhong1234,Moxey Graeme J.1234,Schwich Torsten1234,Morshedi Mahbod1234,Cifuentes Marie P.1234,Humphrey Mark G.1234

Affiliation:

1. Research School of Chemistry

2. Australian National University

3. Canberra

4. Australia

Abstract

Trigonal-bipyramidal molybdenum/tungsten–iridium clusters undergo ligand substitution with isocyanides and triphenylphosphine, and react with alkynes with CC cleavage or triiridium-face-specific addition.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference59 articles.

1. The Chemistry of Metal Cluster Complexes, ed. D. F. Shriver, H. D. Kaesz and R. D. Adams, VCH, New York, 1990

2. Physics and Chemistry of Metal Cluster Complexes, ed. L. L. de Jongh, Kluwer, Amsterdam, 1994

3. P. Braunstein , L. A.Oro and P. R.Raithby, Metal Clusters in Chemistry, Wiley-VCH, Weinheim, Germany, 1999

4. R. D. Adams and F. A.Cotton, Catalysis by Di- and Polynuclear Metal Cluster Complexes, Wiley-VCH, New York, 1998

5. Nanosized (μ12-Pt)Pd164-xPtx(CO)72(PPh3)20 (x ≈ 7) Containing Pt-Centered Four-Shell 165-Atom Pd−Pt Core with Unprecedented Intershell Bridging Carbonyl Ligands:  Comparative Analysis of Icosahedral Shell-Growth Patterns with Geometrically Related Pd145(CO)x(PEt3)30 (x ≈ 60) Containing Capped Three-Shell Pd145 Core

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