Direct catalytic oxyamination of benzene to aniline over Cu(ii) nanoclusters supported on CuCr2O4 spinel nanoparticles via simultaneous activation of C–H and N

Direct catalytic oxyamination of benzene to aniline over Cu(ii) nanoclusters supported on CuCr2O4 spinel nanoparticles via simultaneous activation of C–H and N–H bonds

Published:2014 Issue:87 Volume:50 Page:13311-13314
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Acharyya Shankha S.¹²³,Ghosh Shilpi¹²³,Bal Rajaram¹²³

Affiliation:

1. Catalytic Conversion & Processes Division

2. CSIR-Indian Institute of Petroleum

3. Dehradun-248005, India

Abstract

We report the facile synthesis of a highly efficient, reusable catalyst comprising Cu(ii) nanoclusters supported on CuCr₂O₄ spinel nanoparticles for the oxyamination of benzene to aniline (H₂O₂ + NH₃) under mild aqueous reaction conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC02937B

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