Main chain selective polymer degradation: controlled by the wavelength and assembly

Author:

Do Phuong T.12,Sbordone Federica12,Kalmer Henrik12,Sokolova Anna3ORCID,Zhang Chao124ORCID,Thai Linh Duy12,Golberg Dmitri V.12ORCID,Chapman Robert56ORCID,Poad Berwyck L. J.124ORCID,Frisch Hendrik12ORCID

Affiliation:

1. School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia

2. Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia

3. Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation (ANSTO), New Illawarra Road, Lucas Heights, NSW 2234, Australia

4. Central Analytical Research Facility, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia

5. Centre for Advanced Macromolecular Design, School of Chemistry, UNSW Sydney, Kensington, NSW 2052, Australia

6. School of Environmental and Life Sciences, University of Newcastle, Callaghan, NSW 2308, Australia

Abstract

A pair of cyclic monomers enables selective photocleavage at different wavelengths and self-assembly into photoreactive micelles, which alter depolymerization products.

Funder

Australian Research Council

Australian Nuclear Science and Technology Organisation

Australian Government

Queensland University of Technology

Publisher

Royal Society of Chemistry (RSC)

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