Regio/site-selective alkylation of substrates containing a cis-, 1,2- or 1,3-diol with ferric chloride and dipivaloylmethane as the catalytic system-Reference-Cited by-同舟云学术

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Regio/site-selective alkylation of substrates containing a cis-, 1,2- or 1,3-diol with ferric chloride and dipivaloylmethane as the catalytic system

Published:2020 Issue:4 Volume:22 Page:1139-1144
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Lv Jian¹²³⁴⁵,Liu Yu¹²³⁴⁵,Zhu Jia-Jia¹²³⁴⁵,Zou Dapeng⁶⁷⁸⁹,Dong Hai¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Material Chemistry for Energy Conversion and Storage

2. Ministry of Education

3. School of Chemistry & Chemical Engineering

4. Huazhong University of Science & Technology

5. 430074 Wuhan

6. The College of Chemistry

7. Zhengzhou University

8. Zhengzhou 450052

9. P. R. China

Abstract

We reported the regio/site-selective alkylation of diols and polyols with FeCl₃ as a key catalyst and confirmed the mechanism.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/GC/C9GC04126E

Reference44 articles.

1. A One-Pot Method for Removal of Thioacetyl Group via Desulfurization under Ultraviolet Light To Synthesize Deoxyglycosides

2. Regio/Stereoselective Glycosylation of Diol and Polyol Acceptors in Efficient Synthesis of Neu5Ac-α-2,3-LacNPhth Trisaccharide

3. “One-Pot” Protection, Glycosylation, and Protection–Glycosylation Strategies of Carbohydrates

4. Synthesis and Stereocontrolled Equatorially Selective Glycosylation Reactions of a Pseudaminic Acid Donor: Importance of the Side-Chain Conformation and Regioselective Reduction of Azide Protecting Groups

5. Straightforward S–S Bond Formation via the Oxidation of S-Acetyl by Iodine in the Presence of N-Iodosuccinimide

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2. Regioselective Glycosylation of Mannoside and Galactoside Acceptors Containing 2,4-OH Achieved by Altering Protecting Groups at the 1,3,6-Positions;The Journal of Organic Chemistry;2024-06-03

3. Boronic Acid/Palladium Hybrid Catalysis for Regioselective O-Allylation of Carbohydrates;The Journal of Organic Chemistry;2024-01-09

4. Synthesis and Cytotoxicity of Monomethylated Betulinic Acid 3-O-α-l-Rhamnopyranosides;ACS Omega;2023-09-22

5. Site-selective carbamoylation of carbohydrates catalyzed by SnCl₂/Me₂SnCl₂leading to complementary selectivity;Organic Chemistry Frontiers;2023

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