Unprecedented copper(ii) mediated in situ formation of gem-diol binuclear complexes: a combined experimental and computational study

Author:

Patel Ram N.1234,Singh Yogendra Pratap1234,Singh Yogendra1234,Butcher R. J.5678,Zeller Matthias1910

Affiliation:

1. Department of Chemistry

2. A. P. S. University

3. Rewa

4. India

5. Department of Inorganic & Structural Chemistry

6. Howard University

7. Washington DC

8. 22031 USA

9. Youngstown State University

10. USA

Abstract

The two alkoxo bridged complexes [Cu2(L1)2(HL2)2(H2O)](NO3)2·2H2O 1 and [Cu2(L1)2(HL2)2](NO3)2·H2O 2 have been synthesized by metal assisted hydrolysis with two Schiff bases, where L1 is 2-benzoylpyridine and HL2 is phenyl(pyridin-2-yl)methanediol.

Funder

Ohio Board of Regents

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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