[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra-Reference-Cited by-同舟云学术

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Published:2020 Issue:74 Volume:56 Page:10859-10862
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Ai-Min¹²³⁴^ORCID,Wang Yi¹²³⁴^ORCID,Zavalij Peter Y.¹²³⁴^ORCID,Chen Fu¹²³⁴,Muñoz-Castro Alvaro⁵⁶⁷⁸⁹^ORCID,Eichhorn Bryan W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Maryland

3. College Park

4. USA

5. Laboratorio de Química Inorgánica y Materiales Moleculares

6. Facultad de Ingeniería

7. Universidad Autonoma de Chile

8. Llano Subercaseaux 2801

9. San Miguel

Abstract

Cluster anions [Cp*RuPb₁₁]³⁻ (1) and [Cu@Cp*RuPb₁₁]²⁻ (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Office of Naval Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC03656K

Reference56 articles.

1. Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals

2. Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

3. Interpenetrating As 20 Fullerene and Ni 12 Icosahedra in the Onion-Skin [As@Ni 12 @As 20 ] 3 Ion

4. A Bronze Matryoshka: The Discrete Intermetalloid Cluster [Sn@Cu12@Sn20]12– in the Ternary Phases A12Cu12Sn21 (A = Na, K)

5. THE ISOLATION OF THE ICOSAHEDRAL B12H12-2 ION

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