Trisubstituted geminal diazaalkene derived transient 1,2-carbodications

Author:

Mandal Debdeep123,Stein Felix45678,Chandra Shubhadeep45678,Neuman Nicolás I.45678ORCID,Sarkar Pallavi910113,Das Shubhajit910113,Kundu Abhinanda123,Sarkar Arighna123,Rawat Hemant123,Pati Swapan K.910113ORCID,Chandrasekhar Vadapalli1231213ORCID,Sarkar Biprajit45678ORCID,Jana Anukul123ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad

2. Hyderabad 500107

3. India

4. Institut für Chemie und Biochemie

5. Anorganische Chemie

6. Freie Universität Berlin

7. Fabeckstraße 34-36, 14195

8. Germany

9. Theoretical Sciences Unit

10. Jawaharlal Nehru Centre for Advanced Scientific Research

11. Bangalore 560064

12. Department of Chemistry Indian Institute of Technology Kanpur

13. Kanpur 208016

Abstract

2-Pyrrolidinyl appended trisubstituted geminal diazaalkenes were used for the synthesis of intramolecular base-stabilized dications under 2-e oxidation.

Funder

Tata Institute of Fundamental Research

Department of Atomic Energy, Government of India

Department of Science and Technology, Ministry of Science and Technology

Council of Scientific and Industrial Research, India

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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