Exploration of unconventional π–hole and C–H⋯H–C types of supramolecular interactions in a trinuclear Cd(ii) and a heteronuclear Cd(ii)–Ni(ii) complex and experimental evidence for preferential site selection of the ligand by 3d and 4d metal ions
Author:
Affiliation:
1. Department of Chemistry
2. Jadavpur University
3. Kolkata-700032, India
4. Departament de Química
5. Universitat de les Illes Balears
6. 07122 Palma (Baleares), Spain
Abstract
We report the synthesis of a trinuclear cadmium(ii) (1) and a di(phenoxido)-bridged dinuclear cadmium(ii)–nickel(ii) (2) complex derived from a bicompartmental (N2O4) Schiff base ligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA04428J
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