Exploring the ultrafast and isomer-dependent photodissociation of iodothiophenes via site-selective ionization

Author:

Razmus Weronika O.1,Allum Felix234ORCID,Harries James5,Kumagai Yoshiaki6ORCID,Nagaya Kiyonobu7,Bhattacharyya Surjendu8,Britton Mathew3,Brouard Mark2ORCID,Bucksbaum Philip H.3,Cheung Kieran2,Crane Stuart W.9ORCID,Fushitani Mizuho10ORCID,Gabalski Ian311ORCID,Gejo Tatsuo12,Ghrist Aaron3411ORCID,Heathcote David2ORCID,Hikosaka Yasumasa13ORCID,Hishikawa Akiyoshi1014ORCID,Hockett Paul15ORCID,Jones Ellen2,Kukk Edwin16,Iwayama Hiroshi17,Lam Huynh V. S.8ORCID,McManus Joseph W.2ORCID,Milesevic Dennis2ORCID,Mikosch Jochen18,Minemoto Shinichirou19,Niozu Akinobu20,Orr-Ewing Andrew J.21ORCID,Owada Shigeki2223,Rolles Daniel8ORCID,Rudenko Artem8,Townsend Dave9ORCID,Ueda Kiyoshi2425,Unwin James2,Vallance Claire2ORCID,Venkatachalam Anbu8ORCID,Wada Shin-ichi20ORCID,Walmsley Tiffany2ORCID,Warne Emily M.2ORCID,Woodhouse Joanne L.1ORCID,Burt Michael2ORCID,Ashfold Michael N. R.21ORCID,Minns Russell S.1ORCID,Forbes Ruaridh4ORCID

Affiliation:

1. School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK

2. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3TA, UK

3. PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA

4. Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA

5. QST, SPring-8, Kouto 1-1-1, Sayo, Hyogo, Japan

6. Department of Applied Physics, Tokyo University of Agriculture and Technology, Tokyo, Japan

7. Department of Physics, Kyoto University, Kyoto 606-8502, Japan

8. J.R. Macdonald Laboratory, Department of Physics, Kansas State University, Manhattan, Kansas 66506, USA

9. Institute of Photonics and Quantum Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

10. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan

11. Department of Applied Physics, Stanford University, Stanford, California 94305, USA

12. Graduate School of Material Science, University of Hyogo, Kuoto 3-2-1, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

13. Institute of Liberal Arts and Sciences, University of Toyama, Toyama 930-0194, Japan

14. Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan

15. National Research Council of Canada, 100 Sussex Dr, Ottawa, ON K1A 0R6, Canada

16. Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland

17. Institute for Molecular Science, Okazaki 444-8585, Japan

18. Department of Physics, University of Kassel, Heinrich-Plett-Strasse 40, 34132 Kassel, Germany

19. Department of Physics, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

20. Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8526, Japan

21. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK

22. RIKEN SPring-8 Center, Sayo, Hyogo, 679-5148, Japan

23. Japan Synchrotron Radiation Research Institute, Hyogo, Japan

24. Department of Chemistry, Tohoku University, Sendai 980-8578, Japan

25. Department of Condensed Matter Physics and Photon Science, School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

Abstract

The dissociation dynamics of UV pumped iodothiophene molecules are investigated using velocity map ion imaging, in combination with site-selective extreme ultraviolet ionization of the iodine atom.

Funder

Science and Technology Facilities Council

Japan Society for the Promotion of Science

Leverhulme Trust

Engineering and Physical Sciences Research Council

Basic Energy Sciences

SLAC National Accelerator Laboratory

University of Southampton

Chemical Sciences, Geosciences, and Biosciences Division

European Research Council

Publisher

Royal Society of Chemistry (RSC)

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