Trifluoromethoxy-substituted nickel catalysts for producing highly branched polyethylenes: impact of solvent, activator and N,N′-ligand on polymer properties

Author:

Liu Ming12ORCID,Zhang Randi1,Ma Yanping1ORCID,Han Mingyang12,Solan Gregory A.13,Yang Wenhong1ORCID,Liang Tongling1ORCID,Sun Wen-Hua124ORCID

Affiliation:

1. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. CAS Research/Education Center for Excellence in Molecular Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

3. Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, UK

4. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Abstract

Highly branched and narrowly dispersed polyethylenes with high or ultra-high molecular weights are accessible using the depicted nickel precatalyst/activator combinations.

Funder

Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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