N⋯I halogen bonding supported stabilization of a discrete pseudo-linear [I12]2−polyiodide-Reference-Cited by-同舟云学术

N⋯I halogen bonding supported stabilization of a discrete pseudo-linear [I12]2−polyiodide

Published:2015 Issue:8 Volume:17 Page:1736-1740
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Peuronen Anssi¹²³⁴,Rinta Heikki¹²³⁴,Lahtinen Manu¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Jyväskylä

3. FI-40014 University of Jyväskylä

4. , Finland

Abstract

An unprecedented discrete nearly linear dodecaiodide, [I₁₂]²⁻, can be stabilizedviaN⋯I and cation⋯I⁻interactions using a dicationic template based on the 1,4-diazabicyclo[2.2.2]octane (DABCO) diamine.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CE/C4CE01866D

Reference29 articles.

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3. Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems

4. Dimensional encapsulation of I−⋯I2⋯I− in an organic salt crystal matrix

5. Anion–π Interactions in Salts with Polyhalide Anions: Trapping of I 4 2−

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