A vitamin B12 derivative catalyzed electrochemical trifluoromethylation and perfluoroalkylation of arenes and heteroarenes in organic media

Author:

Hossain Md. Jakir12345,Ono Toshikazu12345ORCID,Wakiya Kosuke12345,Hisaeda Yoshio12345ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Graduate School of Engineering

3. Kyushu University

4. Fukuoka 819-0395

5. Japan

Abstract

The electrochemical trifluoromethylation and perfluoroalkylation of aromatic compounds mediated by a vitamin B12 derivative as a cobalt-based catalyst has been developed.

Funder

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference62 articles.

1. Vitamin B12 and B12-Protein, ed. B. Kräutler, D. Arigoni and B. T. Golding, Wiley-VCH, Weinheim, 1998

2. Chemistry and Biochemistry of B12, ed. R. Banerjee, Wiley-Interscience, New York, 1999

3. The Many Faces of Vitamin B12: Catalysis by Cobalamin-Dependent Enzymes

4. Radical Catalysis in Coenzyme B12-Dependent Isomerization (Eliminating) Reactions

5. Chemistry and Enzymology of Vitamin B12

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