Finding a mononuclear cobalt(<scp>iii</scp>)-peroxo complex with 1,4,7,10-tetraazacyclododecane, an intermediate for dioxygen reduction-Reference-Cited by-同舟云学术

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Finding a mononuclear cobalt(iii)-peroxo complex with 1,4,7,10-tetraazacyclododecane, an intermediate for dioxygen reduction

Published:2023 Issue:47 Volume:47 Page:21648-21653
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Zhang Yan¹²,Qi Xiao-Fang¹,Li Can-Hao¹,Zhan Shu-Zhong¹^ORCID

Affiliation:

1. Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China

2. City College of Dongguan University of Technology, Dongguan 523419, China

Abstract

1,4,7,10-Tetraazacyclododecane (L) reacts with CoCl2 to give [Co(L)(Cl)2]Cl. The introduction of O2 leads to formation of a cobalt(iii)-peroxo species, [L-Co-OO]+, which is responsible for O2 reduction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ04108E

Reference44 articles.

1. Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

2. Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes

3. Recent Advances in Electrocatalysts for Oxygen Reduction Reaction

4. A perspective on low-temperature solid oxide fuel cells

5. What Are Batteries, Fuel Cells, and Supercapacitors?

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1. Synthesis, structure, and catalytic behaviour for oxygen reduction of a µ2-OH-bridged binuclear cobalt complex;2024-01-22

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