The complete mechanism of an aldol condensation in water-Reference-Cited by-同舟云学术

The complete mechanism of an aldol condensation in water

Published:2022 Issue:31 Volume:24 Page:18978-18982
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Perrin Charles L¹^ORCID,Kim Jiwoo¹

Affiliation:

1. Dept. of Chemistry & Biochemistry, Univ. Calif. San Diego, La Jolla, CA, 92093-0358, USA

Abstract

The base-catalyzed aldol condensation between benzaldehyde and p-acetylbenzoic acid in water shows an inverse solvent kinetic isotope effect, k3,D2O/k3,H2O, of 1.33 ± 0.03.

Funder

University of California, San Diego

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02095E

Reference14 articles.

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3. Carbonyl Reactions. II. The Role of the Intermediate Ketol in the Kinetics of the Formation of Chalcone1

4. CRC Handbook of Chemistry and Physics , ed. D. R. Lide , Internet Version, 96 edn, 2016 , https://hbcpnetbase.com

5. Topography of the free energy landscape of Claisen–Schmidt condensation: solvent and temperature effects on the rate-controlling step

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