Catalytic behaviour of the Cu(i)/L/TEMPO system for aerobic oxidation of alcohols – a kinetic and predictive model

Author:

Al-Hunaiti Afnan1ORCID,Abu-Radaha Batool1,Wraith Darren2,Repo Timo3ORCID

Affiliation:

1. Department of Chemistry, School of Science, The University of Jordan, Amman 11942, Jordan

2. School of Public Health and Social Work, Queensland University of Technology, Queensland 4000, Australia

3. Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, 00014 Helsinki, Finland

Abstract

Here, we disclose a new copper(i)-Schiff base complex series for selective oxidation of primary alcohols to aldehydes under benign conditions. Both benzylic and aliphatic alcohols were converted to aldehydes selectively with 99% yield.

Funder

University of Jordan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference39 articles.

1. M.Hudlicky , Oxidations in Organic Chemistry , American Chemical Society , Washington DC , 1990

2. Aerobic oxidation catalysis with stable radicals

3. Mn(ii) acetate: an efficient and versatile oxidation catalyst for alcohols

4. Synthesis and Characterization of Novel Phyto-Mediated Catalyst, and Its Application for a Selective Oxidation of (VAL) into Vanillin under Visible Light

5. G.Tojo and M. I.Fernandez , Oxidation of Alcohols to Aldehydes and Ketones , Springer Verlag , New York , 2006

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3