Catalytic behaviour of the Cu(i)/L/TEMPO system for aerobic oxidation of alcohols – a kinetic and predictive model

Author:

Al-Hunaiti Afnan1ORCID,Abu-Radaha Batool1,Wraith Darren2,Repo Timo3ORCID

Affiliation:

1. Department of Chemistry, School of Science, The University of Jordan, Amman 11942, Jordan

2. School of Public Health and Social Work, Queensland University of Technology, Queensland 4000, Australia

3. Department of Chemistry, Laboratory of Inorganic Chemistry, University of Helsinki, 00014 Helsinki, Finland

Abstract

Here, we disclose a new copper(i)-Schiff base complex series for selective oxidation of primary alcohols to aldehydes under benign conditions. Both benzylic and aliphatic alcohols were converted to aldehydes selectively with 99% yield.

Funder

University of Jordan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference39 articles.

1. M.Hudlicky , Oxidations in Organic Chemistry , American Chemical Society , Washington DC , 1990

2. Aerobic oxidation catalysis with stable radicals

3. Mn(ii) acetate: an efficient and versatile oxidation catalyst for alcohols

4. Synthesis and Characterization of Novel Phyto-Mediated Catalyst, and Its Application for a Selective Oxidation of (VAL) into Vanillin under Visible Light

5. G.Tojo and M. I.Fernandez , Oxidation of Alcohols to Aldehydes and Ketones , Springer Verlag , New York , 2006

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