Effect of the heteroatom on the magnetic and luminescence properties of hybrid lanthanide-substituted Keggin-type polyoxometalates-Reference-Cited by-同舟云学术

Effect of the heteroatom on the magnetic and luminescence properties of hybrid lanthanide-substituted Keggin-type polyoxometalates

Published:2024 Issue:32 Volume:53 Page:13330-13334
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bustamante-Fernández Janire¹²^ORCID,Ruiz-Bilbao Estibaliz²^ORCID,Rodríguez-Esteban Corina²^ORCID,Gonidec Mathieu³^ORCID,García José A.⁴,Lezama Luis¹^ORCID,Gutiérrez-Zorrilla Juan M.¹²^ORCID,Oyarzabal Itziar²⁵^ORCID,Artetxe Beñat¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco UPV/EHU, P.O. Box 644, 48080 Bilbao, Spain

2. BCMaterials, Edificio Martina Casiano, 3rd Floor, UPV/EHU Science Park, Barrio Sarriena s/n, 48940 Leioa, Spain

3. Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France

4. Departamento de Física Aplicada II, Facultad de Ciencia y Tecnología. Universidad del País Vasco UPV/EHU, P.O. Box 644, 48080 Bilbao, Spain

5. IKERBASQUE, Basque Foundation for Science, 48009 Bilbao, Spain

Abstract

Replacement of the heteroatom modifies the magneto-luminescence properties of [Ln(α-GeW11O39)(H2L)]5− (Ln = Sm to Lu) hybrid anions. The Yb-derivative exhibits simultaneous slow relaxation of magnetization and NIR emission at room temperature.

Funder

Ministerio de Ciencia e Innovación

Euskal Herriko Unibertsitatea

Eusko Jaurlaritza

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01379D

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5. Recent advances in lanthanide-based POMs for photoluminescent applications