Olefin epoxidation with tert-butyl hydroperoxide catalyzed by MoO2X2L complexes: a DFT mechanistic study
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2006/DT/B515484G
Reference69 articles.
1. Chemistry of molybdenum. Part 7. Reactivity of terminal oxo-ligands in cis-[MoO2(acda)2](Hacda = 2-aminocyclopent-1-ene-1-carbodithioic acid) toward proton- and electron-donor reagents. Synthesis, redox chemistry and spectroscopic characterisation of neutral seven-co-ordinate catecholato and aryldiazenido compounds of molybdenum
2. Model compounds for the active sites of oxo-transfer molybdoenzymes. Synthesis, structural characterization, and electrochemical properties of [NH4]2[MoO2{O2CC(S)Ph2}2]
3. Formation of bis[bis(3,5-di-tert-butylcatecholato)oxomolybdenum(VI)] and related stable molybdenum-catechol complexes
4. Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis
5. Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications
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