Internal 2D networking of silver bromide with a bidentate N-heterocyclic carbene ligand enables the formation of an inherently heterogeneous reusable catalyst for multicomponent A3 coupling

Author:

Nallappan Sundaravelu1,Kucherak Oleksandr1,Kiss Anita1,Lapinskaite Ringaile12,Císařová Ivana3,Rycek Lukas1ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 8, 128 00 Prague, Czech Republic

2. Department of Organic Chemistry, Center for Physical Sciences and Technology, Akademijos g. 7, Vilnius, 08412, Lithuania

3. Department of Inorganic Chemistry, Faculty of Science Charles University, Hlavova 8, 128 00 Prague, Czech Republic

Abstract

We report the synthesis of an internal 2D networking heterogeneous silver catalyst stabilized by bidentate N-heterocyclic carbene ligands. The Ag–NHC catalyst is employed in A3 coupling reactions and demonstrated reusability for six cycles.

Funder

Univerzita Karlova v Praze

Publisher

Royal Society of Chemistry (RSC)

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