Structure and energetics of hydrogen bonding networks in dilute HOD/H<sub>2</sub>O solutions confined in silica nanopores-Reference-Cited by-同舟云学术

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Structure and energetics of hydrogen bonding networks in dilute HOD/H₂O solutions confined in silica nanopores

Published:2023 Issue:11 Volume:10 Page:3025-3038
ISSN:2051-8153
Container-title:Environmental Science: Nano
language:en
Short-container-title:Environ. Sci.: Nano

Author:

Ilgen Anastasia G.¹^ORCID,Senanayake Hasini S.²,Thompson Ward H.²^ORCID,Greathouse Jeffery A.³^ORCID

Affiliation:

1. Geochemistry Department, Sandia National Laboratories, Albuquerque, New Mexico 87185, USA

2. Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA

3. Nuclear Waste Disposal Research & Analysis Department, Sandia National Laboratories, Albuquerque, New Mexico 87185, USA

Abstract

Nanoconfinement in silica nanopores strengthens hydrogen bonds near surfaces, and weakens hydrogen bonds in nanopore volume away from the surfaces.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Environmental Science,Materials Science (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2023/EN/D3EN00291H

Reference63 articles.

1. On the strength of hydrogen bonding within water clusters on the coordination limit

2. Crucial Role of Water in the Formation of Basic Properties of Living Matter

3. Anomalously low dielectric constant of confined water

4. Effect of Hydrogen Bonds on the Dielectric Properties of Interfacial Water

5. Changes in density and surface tension of water in silica pores

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