Physical and chemical properties and degradation of MAPbBr3 films on transparent substrates

Author:

Carpenella Valentina1ORCID,Messina Fabrizio2,Barichello Jessica3,Matteocci Fabio3ORCID,Postorino Paolo4,Petrillo Caterina5,Nucara Alessandro46,Dini Danilo2ORCID,Fasolato Claudia7ORCID

Affiliation:

1. Department of Science, University of Roma Tre, Via della Vasca Navale 84, 00146 Rome, Italy

2. Department of Chemistry, Sapienza University of Rome, P.le A. Moro 5, 00185 Rome, Italy

3. CHOSE, Department of Electronic Engineering, University of Rome Tor Vergata, Rome 00133, Italy

4. Department of Physics, Sapienza University of Rome, Piazzale Aldo Moro 5, 00185 Rome, Italy

5. Department of Physics and Geology, University of Perugia, Via A. Pascoli, 06123 Perugia, Italy

6. CNR-SPIN, c/o Sapienza University of Rome, Piazzale Aldo Moro 5, 00185 Rome, Italy

7. CNR-ISC, Institute for Complex Systems, c/o Sapienza University of Rome, P.le A. Moro 5, 00185 Rome, Italy

Abstract

We explore the physical and chemical degradation mechanisms of methylammonium lead bromide (CH3NH3PbBr3) thin films, depending on the storage conditions. We show that, under vacuum conditions, the NH4Pb2Br5 degradation compound can be formed.

Funder

Sapienza Università di Roma

Ministero dell'Università e della Ricerca

Horizon 2020 Framework Programme

Regione Lazio

Publisher

Royal Society of Chemistry (RSC)

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