Fine-tuning of radiative properties by “mild” substituents: searching for a perfectly soft chromophore-Reference-Cited by-同舟云学术

Fine-tuning of radiative properties by “mild” substituents: searching for a perfectly soft chromophore

Published:2024 Issue:25 Volume:26 Page:17944-17950
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Orzanowska Grażyna¹,Ryppa Claudia²,Senge Mathias O.²^ORCID,Waluk Jacek¹³^ORCID

Affiliation:

1. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

2. School of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, Trinity College Dublin, The University of Dublin, 52-160 Pearse Street, Dublin D02R590, Ireland

3. Faculty of Mathematics and Science, Cardinal Stefan Wyszyński University, Dewajtis 5, 01-815 Warsaw, Poland

Abstract

Absorption, fluorescence, and MCD spectra reveal the energy ordering of two frontier orbitals opposite to that predicted by DFT calculations.

Funder

Narodowe Centrum Nauki

Science Foundation Ireland

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01502A

Reference34 articles.

1. Magnetic circular dichroism of aromatic molecules

2. Determination of positional isomers of methylpyrenes and other polycyclic aromatic hydrocarbons by magnetic circular dichroism

3. Perimeter model and magnetic circular dichroism of porphyrin analogs

4. Magnetic circular dichroism studies. 60. Substituent-induced sign variation in the magnetic circular dichroism spectra of reduced porphyrins. 1. Spectra and band assignments

5. Magnetic circular dichroism studies. 61. Substituent-induced sign variation in the magnetic circular dichroism spectra of reduced porphyrins. 2. Perturbed molecular orbital analysis