Difunctionalization of alkenes proceeding with radical 1,2-alkynyl migration in batch and continuous-flow modes-Reference-Cited by-同舟云学术

Difunctionalization of alkenes proceeding with radical 1,2-alkynyl migration in batch and continuous-flow modes

Published:2024 Issue:4 Volume:48 Page:1735-1740
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mao Ziren¹,Zhou Yiliang¹,Zhang Jingming¹,Liu Chengkou¹,Wang Chang-Sheng¹,Yang Xiaobing²,Qin Hong¹,Fang Zheng¹^ORCID,Guo Kai¹³^ORCID

Affiliation:

1. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, 211816, China

2. China Biology and Medicine Department, Jiangsu Industrial Technology Research Institute, Nanjing 210031, P. R. China

3. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 211816, China

Abstract

A straightforward method for electrochemical difunctionalization of alkenes to construct the corresponding α-alkynyl ketone product under catalyst- and oxidant-free conditions in batch and continuous-flow modes was developed.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Jiangsu National Synergistic Innovation Center for Advanced Materials

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D3NJ05081E

Reference33 articles.

1. Recent Advances in Radical C–H Activation/Radical Cross-Coupling

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4. Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides

5. Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols