Fast reductive defluorination of branched perfluorooctane sulfonic acids by cobalt phthalocyanine: electrochemical studies and mechanistic insights-Reference-Cited by-同舟云学术

Fast reductive defluorination of branched perfluorooctane sulfonic acids by cobalt phthalocyanine: electrochemical studies and mechanistic insights

Published:2024 Issue:1 Volume:10 Page:216-227
ISSN:2053-1400
Container-title:Environmental Science: Water Research & Technology
language:en
Short-container-title:Environ. Sci.: Water Res. Technol.

Author:

Mirabediny Maryam¹,Yu Tsz Tin¹^ORCID,Sun Jun¹,Lee Matthew²,O'Carroll Denis M.²^ORCID,Manefield Michael J.²,Åkermark Björn³^ORCID,Das Biswanath³^ORCID,Kumar Naresh¹^ORCID

Affiliation:

1. School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia

2. School of Civil and Environmental Engineering, Water Research Centre, The University of New South Wales, Sydney, NSW 2052, Australia

3. Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Svante Arrhenius väg 16C, SE-10691 Stockholm, Sweden

Abstract

CobaltII phthalocyanine in the presence of TiIII citrate acts as an efficient reducing agent which was able to defluorinate 54.5% of all branched PFOS isomers.

Funder

Australian Research Council

Stockholms Universitet

Publisher

Royal Society of Chemistry (RSC)

Subject

Water Science and Technology,Environmental Engineering

Link

http://pubs.rsc.org/en/content/articlepdf/2024/EW/D3EW00612C

Reference36 articles.

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3. Multi-industry per- and polyfluoroalkyl substances (PFAS) study – Preliminary Report , United States Environmental Protection Agency (EPA) , September 2021

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5. Half-Life of Serum Elimination of Perfluorooctanesulfonate,Perfluorohexanesulfonate, and Perfluorooctanoate in Retired Fluorochemical Production Workers

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