Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium(vi) complex

Author:

Dhuri Sunder N.12345,Lee Yong-Min12345,Seo Mi Sook12345,Cho Jaeheung12345,Narulkar Dattaprasad D.6789,Fukuzumi Shunichi12345,Nam Wonwoo12345

Affiliation:

1. Department of Chemistry and Nano Science

2. Center for Biomimetic System

3. Ewha Womans University

4. Seoul 120-750

5. Korea

6. Department of Chemistry

7. Goa University

8. Goa

9. India

Abstract

Valuable insights into the hydride-transfer mechanism and C–H bond activation reactions by high-valent trans-dioxoruthenium(vi) species is provided.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference90 articles.

1. R. A. Sheldon and J. K.Kochi, Metal-Catalyzed Oxidations of Organic Compounds, Academic Press, New York, 1981

2. B. Meunier , Biomimetic Oxidations Catalyzed by Transition Metal Complexes, Imperial College Press, London, 1998

3. P. R. Ortiz de Montellano , Cytochrome P450: Structure, Mechanism, and Biochemistry, Kluwer Academic/Plenum Publishers, New York, 3rd edn, 2005

4. Non-Heme Fe(IV)–Oxo Intermediates

5. The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

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