Metal-to-metal electron transfer in a cyanido-bridged {Fe<sub>2</sub>Co<sub>2</sub>} square complex followed by X-ray diffraction and absorption techniques-Reference-Cited by-同舟云学术

Metal-to-metal electron transfer in a cyanido-bridged {Fe₂Co₂} square complex followed by X-ray diffraction and absorption techniques

Published:2022 Issue:86 Volume:58 Page:12098-12101
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mathonière Corine¹²^ORCID,Mitcov Dmitri¹^ORCID,Koumousi Evangelia¹²,Amorin-Rosario Daniel¹,Dechambenoit Pierre¹,Fatima Jafri Sadaf³,Sainctavit Philippe³,Cartier dit Moulin Christophe⁴,Toupet Loic⁵,Trzop Elzbieta⁵^ORCID,Collet Eric⁵^ORCID,Arrio Marie-Anne³^ORCID,Rogalev Andrei⁶,Wilhelm Fabrice⁶,Clérac Rodolphe¹^ORCID

Affiliation:

1. Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, CRPP, UMR 5031, 33600 Pessac, France

2. Univ. Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, 33600 Pessac, France

3. Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, CNRS UMR7590, Sorbonne Université, MNHN, 75252 Cedex 5, Paris, France

4. Institut Parisien de Chimie Moléculaire, IPCM, Sorbonne Université, CNRS, F-75005 Paris, France

5. Univ. Rennes, CNRS, Institut de Physique de Rennes (IPR) – UMR 6251, F-35000 Rennes, France

6. ESRF – The European Synchrotron, 38043 Grenoble, France

Abstract

Combining X-ray diffraction and absorption spectroscopy, a full picture of the thermal-, light- and X-ray-induced metal-to-metal electron transfer in a cyanido-bridged molecular Fe/Co square is obtained, demonstrating the concerted and concomitant role played by the Fe and Co sites.

Funder

Centre National de la Recherche Scientifique

Association Sorbonne Université

Université de Rennes 1

European Synchrotron Radiation Facility

Université de Bordeaux

Sorbonne Université

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04246K

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