Synthesis of labile all-trans-7,8,7′,8′-bis-acetylenic carotenoids by bi-directional Horner–Wadsworth–Emmons condensation-Reference-Cited by-同舟云学术

Synthesis of labile all-trans-7,8,7′,8′-bis-acetylenic carotenoids by bi-directional Horner–Wadsworth–Emmons condensation

Published:2015 Issue:10 Volume:13 Page:3024-3031
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Vaz Belén¹²³⁴⁵,Fontán Noelia¹²³⁴⁵,Castiñeira Marta¹²³⁴⁵,Álvarez Rosana¹²³⁴⁵,de Lera Ángel R.¹²³⁴⁵

Affiliation:

1. Department of Organic Chemistry and Center for Biomedical Research (CINBIO)

2. IBIV

3. Universidade de Vigo

4. 36310 Vigo

5. Spain

Abstract

Two symmetrical C₇,C₈-acetylenic carotenoids have been stereoselectively prepared using a bi-directional Horner–Wadsworth–Emmons condensation of the C₁₀-dialdehyde and C₁₅-phosphonates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02144D

Reference49 articles.

1. Functions, Therapeutic Applications, and Synthesis of Retinoids and Carotenoids

2. G. Britton , S.Liaaen-Jensen and H. E.Pfander, Carotenoids. Part 1A. Isolation and Analysis, Birkhäuser, Basel, 1995

3. Carotenoids. Part 1B. Spectroscopy, ed. G. Britton, S. Liaaen-Jensen and H. Pfander, Birkhäuser, Basel, 1995

4. G. Britton , S.Liaaen-Jensen and H.Pfander, Carotenoids. Vol. 4. Natural Functions, Birkhäuser, Basel, 2008

5. Reaction Dynamics of Flavonoids and Carotenoids as Antioxidants

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stereoselective Synthesis of Bisfuranoxide (Aurochrome, Auroxanthin) and Monofuranoxide (Equinenone 5′,8′-Epoxide) Carotenoids by Double Horner–Wadsworth–Emmons Reaction;Journal of Natural Products;2022-09-19

2. Total Synthesis and Biological Evaluation of Heliolactone;Helvetica Chimica Acta;2019-10-21

3. Stereocontrolled synthesis and configurational assignment of (R)-all-trans-11,12-dihydro-3-hydroxyretinol;Tetrahedron Letters;2019-08

4. Recent topics of the natural product synthesis by Horner–Wadsworth–Emmons reaction;Tetrahedron Letters;2018-02

5. The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2015;Coordination Chemistry Reviews;2016-12