Photoswitching of arylazopyrazoles upon S1 (nπ*) excitation studied by transient absorption spectroscopy and ab initio molecular dynamics

Author:

Reichenauer Till1,Böckmann Marcus2,Ziegler Katharina3,Kumar Vikas1,Ravoo Bart Jan3ORCID,Doltsinis Nikos L.2ORCID,Schlücker Sebastian1ORCID

Affiliation:

1. Physical Chemistry I and Center for Nanointegration Duisburg-Essen (CENIDE), Universität Duisburg-Essen, 45141 Essen, Germany

2. Institute of Solid-State Theory and Center for Multiscale Theory and Computation, Universität Münster, 48149 Münster, Germany

3. Organic Chemistry Institute and Center for Soft Nanoscience (SoN), Universität Münster, 48148 Münster, Germany

Abstract

Arylazopyrazoles (AAPs) are an important class of molecular photoswitches with high photostationary states (PSS) and long thermal lifetimes.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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