First structural evidence of a Se–Br–Br halogen-bonded molecular complex-Reference-Cited by-同舟云学术

First structural evidence of a Se–Br–Br halogen-bonded molecular complex

Published:2017 Issue:9 Volume:41 Page:3606-3611
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Torubaev Yury V.¹²³⁴^ORCID,Skabitskiy Ivan V.¹²³⁴,Pavlova Alina V.¹²³⁴,Pasynskii Alexander A.¹²³⁴

Affiliation:

1. N.S. Kurnakov Institute of General and Inorganic Chemistry

2. Russian Academy of Sciences 119991

3. Moscow

4. Russian Federation

Abstract

Bromination of the bicyclic selenoether (2,6-dibromo-9-selenabicyclo[3.3.1]-nonane) affords the products ranging from the unique molecular complex C₈H₁₂Br₂Se–Br₂ to the ionic polybromide complex [C₈H₁₂Br₂SeBr⁺]Br₅.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ04096A

Reference36 articles.

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4. First coordination compounds of SeBr2 with selenium-containing ligands: X-ray structural determination

5. Crystallographic characterisation of dihalogenodimethylselenium compounds, Me2SeX2 (X = Cl, Br or I) and the dependence of their structures on the nature of the halogen

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