Electrochemically driven C–N bond formation from CO<sub>2</sub> and ammonia at the triple-phase boundary-Reference-Cited by-同舟云学术

Electrochemically driven C–N bond formation from CO₂ and ammonia at the triple-phase boundary

Published:2022 Issue:14 Volume:13 Page:3957-3964
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Junnan¹,Kornienko Nikolay¹^ORCID

Affiliation:

1. Department of Chemistry, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, QC H2V 0B3, Canada

Abstract

Electrocatalytic formation of C–N bonds was achieved through the electrolysis of CO2 and NH3 over Cu catalysts. A combined analytical and spectroscopic approach gave insights into the reaction mechanism leading to formamide and acetamide products.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06590D

Reference40 articles.

1. Electrocatalysis as the Nexus for Sustainable Renewable Energy: The Gordian Knot of Activity, Stability, and Selectivity

2. What would it take for renewably powered electrosynthesis to displace petrochemical processes?

3. Can sustainable ammonia synthesis pathways compete with fossil-fuel based Haber–Bosch processes?

4. Strategies for heterogeneous small-molecule electrosynthesis

5. Considerations for the scaling-up of water splitting catalysts

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