Fe- and Mn-modified SO42−/ZrO2 conjoined O2–Ac2O as a composite catalytic system for highly selective nitration of 1-nitronaphthalene with NO2 to valuable 1,5-dinitronaphthalene-Reference-Cited by-同舟云学术

Fe- and Mn-modified SO42−/ZrO2 conjoined O2–Ac2O as a composite catalytic system for highly selective nitration of 1-nitronaphthalene with NO2 to valuable 1,5-dinitronaphthalene

Published:2021 Issue:11 Volume:6 Page:2204-2213
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Yan Jiaqi¹,You Kuiyi¹²^ORCID,Ni Wenjin¹,Duan Ting³,Chen Zhenpan¹^ORCID,Zhao Fangfang¹,Luo He'an¹²

Affiliation:

1. School of Chemical Engineering, Xiangtan University, Xiangtan 411105, P.R. China

2. National & Local United Engineering Research Center for Chemical Process Simulation and Intensification, Xiangtan University, Xiangtan 411105, P. R. China

3. School of Educational Science, Hunan Normal University, Changsha 410081, P. R. China

Abstract

NO2 as benign nitrating agent and Fe–Mn bimetallic modified SZ as catalyst replaced traditional nitric–sulfuric mixed acid systems for 1-NN nitration. The synergism of Fe1.5Mn0.5–SZ and O2–Ac2O significantly improved the selectivity to 1,5-DNN.

Funder

National Natural Science Foundation of China

Key Research and Development Program of Hunan Province of China

Natural Science Foundation of Hunan Province

Scientific Research Foundation of Hunan Provincial Education Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RE/D1RE00269D

Reference74 articles.