Four alkali metal molybdates with two types of Mo–O chains, ABMo3O10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties
Author:
Affiliation:
1. CAS Key Laboratory of Functional Materials and Devices for Special Environments
2. Xinjiang Technical Institute of Physics & Chemistry
3. CAS
4. Xinjiang Key Laboratory of Electronic Information Materials and Devices
5. Urumqi 830011
Abstract
The effects of cation size on the framework structures of four stoichiometrically equivalent alkali metal molybdates were discussed in detail.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01893F
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4. A CsCl-type inorganic cluster-based high-symmetry crystal built from {Mo4.55V7.45PO40}10.45− with a high ratio of vanadium to molybdenum and {(H2O)0.3@K6(H2O)12}6+ clusters exhibiting proton conduction below the freezing point of water;Dalton Transactions;2019
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