Manganese catalyzed α-methylation of ketones with methanol as a C1 source-Reference-Cited by-同舟云学术

Manganese catalyzed α-methylation of ketones with methanol as a C1 source

Published:2019 Issue:3 Volume:55 Page:314-317
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bruneau-Voisine Antoine¹²³⁴⁵^ORCID,Pallova Lenka⁵⁶²⁷⁸,Bastin Stéphanie⁵⁶²⁷⁸^ORCID,César Vincent⁵⁶²⁷⁸^ORCID,Sortais Jean-Baptiste⁵⁶²⁷⁸^ORCID

Affiliation:

1. Univ Rennes

2. CNRS

3. F-35000 Rennes

4. France

5. LCC-CNRS

6. Université de Toulouse

7. UPS

8. Toulouse

Abstract

The direct α-methylation of ketones with methanol under hydrogen borrowing conditions using a well-defined manganese PN³P pre-catalyst was, for the first time, achieved.

Funder

Institut Universitaire de France

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC08064J

Reference59 articles.

1. The Methylation Effect in Medicinal Chemistry

2. Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

3. P. T. Anastas and J. C.Warner , Green Chemistry: Theory and Practice , Oxford University Press , 2000

4. Recent Advances in α-Alkylation Reactions using Alcohols with Hydrogen Borrowing Methodologies

5. Borrowing Hydrogen in the Activation of Alcohols

Cited by 98 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Electrochemical Synthesis of Spirolactones from α-Tetralone Derivatives with Methanol as a C1 Source;Organic Letters;2024-06-03

2. Manganese-catalyzed C–C and C–N bond formation with alcohols via borrowing hydrogen or hydrogen auto-transfer;Beilstein Journal of Organic Chemistry;2024-05-21

3. Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions;Chemical Reviews;2024-04-17

4. Manganese‐Catalyzed Mono‐N‐Methylation of Aliphatic Primary Amines without the Requirement of External High‐Hydrogen Pressure;Angewandte Chemie International Edition;2024-02-19

5. Manganese‐Catalyzed Mono‐N‐Methylation of Aliphatic Primary Amines without the Requirement of External High‐Hydrogen Pressure;Angewandte Chemie;2024-02-19