Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(ii) complexes assembled on Cu(111)-Reference-Cited by-同舟云学术

Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(ii) complexes assembled on Cu(111)

Published:2021 Issue:9 Volume:8 Page:2395-2404
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Kelai Massine¹²³⁴⁵,Cahier Benjamin⁶⁷³⁸⁵,Atanasov Mihail⁹¹⁰¹¹¹²¹³^ORCID,Neese Frank⁹¹⁰¹¹^ORCID,Tong Yongfeng¹²³⁴⁵,Zhang Luqiong⁶⁷³⁸⁵,Bellec Amandine¹²³⁴⁵^ORCID,Iasco Olga⁶⁷³⁸⁵,Rivière Eric⁶⁷³⁸⁵,Guillot Régis⁶⁷³⁸⁵^ORCID,Chacon Cyril¹²³⁴⁵,Girard Yann¹²³⁴⁵,Lagoute Jérôme¹²³⁴⁵,Rousset Sylvie¹²³⁴⁵,Repain Vincent¹²³⁴⁵^ORCID,Otero Edwige¹⁴¹⁵¹⁶¹⁷⁵,Arrio Marie-Anne¹⁴¹⁵¹⁶¹⁷⁵,Sainctavit Philippe¹⁴¹⁵¹⁶¹⁷⁵^ORCID,Barra Anne-Laure¹⁸¹⁹²⁰²¹⁵,Boillot Marie-Laure⁶⁷³⁸⁵^ORCID,Mallah Talal⁶⁷³⁸⁵^ORCID

Affiliation:

1. Université de Paris

2. Laboratoire Matériaux et Phénomènes Quantiques

3. CNRS

4. Paris

5. France

6. Institut de Chimie Moléculaire et des Matériaux d'Orsay

7. Université Paris-Saclay

8. 91405 Orsay Cedex

9. Max-Planck-Institut für Kohlenforschung

10. 45470 Mülheim an der Ruhr

11. Germany

12. Institute of General and Inorganic Chemistry

13. Bulgarian Academy of Sciences

14. Synchrotron SOLEIL

15. L'Orme des Merisiers

16. Saint-Aubin

17. 91192 Gif sur Yvette

18. Laboratoire National des Champs Magnétiques Intenses

19. UPR CNRS 3228

20. Univ. Grenoble Alpes

21. 38042 Grenoble Cedex 9

Abstract

The tris pyrazolyl borate ligand imposes a rigid scaffold around Fe(ii) ensuring a robust magnetic anisotropy when the molecules assembled as monolayers suffer from the dissymmetric environment of the substrate/vacuum interface.

Funder

Horizon 2020 Framework Programme

Centre National de la Recherche Scientifique

Université Paris-Saclay

Institut Universitaire de France

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00085C

Reference33 articles.