Slow magnetic relaxation in penta-coordinate cobalt(ii) field-induced single-ion magnets (SIMs) with easy-axis magnetic anisotropy-Reference-Cited by-同舟云学术

Slow magnetic relaxation in penta-coordinate cobalt(ii) field-induced single-ion magnets (SIMs) with easy-axis magnetic anisotropy

Published:2020 Issue:33 Volume:49 Page:11715-11726
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Massoud Salah S.¹²³⁴¹^ORCID,Perez Zoe E.¹²³⁴,Courson Jessica R.¹²³⁴^ORCID,Fischer Roland C.⁵⁶⁷⁸^ORCID,Mautner Franz A.⁹⁶⁷⁸,Vančo Ján¹⁰¹¹¹²¹³¹⁴,Čajan Michal¹⁰¹¹¹²¹³¹⁴^ORCID,Trávníček Zdeněk¹⁰¹¹¹²¹³¹⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Louisiana at Lafayette

3. Lafayette

4. USA

5. Institut für Anorganische Chemie

6. Technische Universität Graz

7. A-8010 Graz

8. Austria

9. Institut für Physikalische and Theoretische Chemie

10. Regional Centre of Advanced Technologies and Materials

11. Division of Biologically Active Complexes and Molecular Magnets

12. Palacký University in Olomouc

13. CZ-783 71 Olomouc

14. Czech Republic

Abstract

Two penta-coordinate [Co(Lⁿ)(NCS)]ClO₄ with substituted pyridyl based bispyrazolyl ligands have been structurally characterized. The complexes show an easy-axis magnetic anisotropy, large rhombicity and slow relaxation of magnetization.

Funder

University of Louisiana at Lafayette

European Regional Development Fund

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02338H

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1. Electronic read-out of a single nuclear spin using a molecular spin transistor