Ring-fused cyclobutanesviacycloisomerization of alkylidenecyclopropane acylsilanes-Reference-Cited by-同舟云学术

Ring-fused cyclobutanesviacycloisomerization of alkylidenecyclopropane acylsilanes

Published:2020 Issue:20 Volume:11 Page:5294-5298
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Eichenberger Sarah¹²³⁴^ORCID,Hönig Moritz¹²³⁴^ORCID,Richter Matthieu J. R.¹²³⁴^ORCID,Gershoni-Poranne Renana¹²³⁴^ORCID,Carreira Erick M.¹²³⁴^ORCID

Affiliation:

1. Laboratorium für Organische Chemie

2. Eidgenössische Technische Hochschule Zürich, HCI H335

3. 8093 Zürich

4. Switzerland

Abstract

A novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed that involves tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02224A

Reference52 articles.

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5. Total synthesis of -illudol

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