Ring-fused cyclobutanesviacycloisomerization of alkylidenecyclopropane acylsilanes
Author:
Affiliation:
1. Laboratorium für Organische Chemie
2. Eidgenössische Technische Hochschule Zürich, HCI H335
3. 8093 Zürich
4. Switzerland
Abstract
A novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed that involves tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02224A
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