DFT studies of two-electron oxidation, photochemistry, and radical transfer between metal centres in the formation of platinum(iv) and palladium(iv) selenolates from diphenyldiselenide and metal(ii) reactants-Reference-Cited by-同舟云学术

DFT studies of two-electron oxidation, photochemistry, and radical transfer between metal centres in the formation of platinum(iv) and palladium(iv) selenolates from diphenyldiselenide and metal(ii) reactants

Published:2020 Issue:39 Volume:49 Page:13566-13572
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Canty Allan J.¹²³⁴^ORCID,Ariafard Alireza¹²³⁴^ORCID,Puddephatt Richard J.⁵⁶⁷⁸^ORCID

Affiliation:

1. School of Natural Sciences – Chemistry

2. University of Tasmania

3. Hobart

4. Australia

5. Department of Chemistry

6. University of Western Ontario

7. London

8. Canada N6A 5B

Abstract

Excitation by light to the M–M antibonding orbital of [M^IIIMe₂(2,2′-bipyridine)(SePh)]₂ releases 2[M^IIIMe₂(bipy)(SePh)]˙; the doublets react to give M^IVMe₂(bipy)(SePh)₂ and M^IIMe₂(bipy).

Funder

Australian Research Council

National Computational Infrastructure

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02978E

Reference23 articles.

1. Oxidative addition of E–E bonds (E = Group 16 element) to platinum(II): a route to platinum(IV) thiolate and selenolate complexes

2. Oxidation of Complexes by (O2CPh)2 and (ER)2 (E = S, Se), Including Structures of Pd(CH2CH2CH2CH2)(SePh)2(bpy) (bpy = 2,2‘-Bipyridine) and MMe2(SePh)2(L2) (M = Pd, Pt; L2 = bpy, 1,10-Phenanthroline) and C···O and C···E Bond Formation at Palladium(IV)

3. SnBrMe3 and dichalcogenides (ER)2 as oxidants: Synthesis of platinum(IV) complexes, and C⋯C and C⋯E coupling from pallada(IV)cyclopentane complexes and PdMe2(EPh){(pz)3BH} {E=O2C, S, Se; [(pz)3BH]−=tris(pyrazol-1-yl)borate}

4. Reversible oxidative addition of a diaryl diselenide to a diorganopalladium(II) complex, carbon–selenium bond formation at palladium(IV), and structural studies of palladium(II) and platinum(IV) selenolates

5. Fine-Tuning the Basicity of Metal Complexes: Reversible Oxidative Addition of Se−Se Bonds to Platinum(II) Precursors

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