Preparation, characterization and DFT+U study of the polar Fe3+-based phase Ba5Fe2ZnIn4S15 containing S = 5/2 zigzag chains-Reference-Cited by-同舟云学术

Preparation, characterization and DFT+U study of the polar Fe³⁺-based phase Ba₅Fe₂ZnIn₄S₁₅ containing S = 5/2 zigzag chains

Published:2022 Issue:24 Volume:51 Page:9522-9530
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Almoussawi Batoul¹,Duffort Victor¹^ORCID,Arevalo-Lopez Angel M.¹^ORCID,Braun Maxime¹,Djelal Nora¹,Kabbour Houria¹^ORCID

Affiliation:

1. Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille, France

Abstract

The polar chalcogenide phase Ba5Fe2ZnIn4S15 possesses weakly interacting magnetic zig-zag chains made of corner-sharing Fe3+S4 thus forming an AFM S = 5/2 spin chain system. The intrinsic polarization is mostly due to the anionic framework.

Funder

Centre National de la Recherche Scientifique

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00733A

Reference26 articles.

1. A.Abudurusuli , K.Wu , J.Li , A.Yalikun , Z.Yang and S.Pan , LiBa 2 M , 2019 , vol. 4 . 10.1021/acs.inorgchem.9b01810

2. N.Nakayama , Studies on the Compounds in the Ba-Fe-S Antiferromagnetism of Ba, FeS, and Related System. I. Linear Chain Compounds Ba & OS , 1980 , vol. 356 , pp. 351–356

3. J. T.Lemley , Ba, Fe, S, and Ba, FeS: Crystal Structures, Miissbauer, Magnetic, and Electrical Behavior , 1976 , vol. 128 , pp. 117–128

4. Effects of Cr doping on the superconductivity and magnetism of FeTe0.8S0.2

5. Plausible multiferroic and magneto-electric behaviour of polycrystalline Bi0.85Gd0.05La0.1FeO3 at room temperature