Synthesis, characterization and theoretical calculations of model compounds of silanols catalyzed by TEMPO to elucidate the presence of Si–O–Si and Si–O

Synthesis, characterization and theoretical calculations of model compounds of silanols catalyzed by TEMPO to elucidate the presence of Si–O–Si and Si–O–N bonds

Published:2015 Issue:97 Volume:5 Page:79829-79844
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Percino Judith¹²³⁴⁵,Pacheco José A.¹²³⁴⁵,Soriano-Moro Guillermo¹²³⁴⁵,Cerón Margarita¹²³⁴⁵,Castro M. Eugenia¹²³⁴⁵,Chapela Víctor M.¹²³⁴⁵,Bonilla-Cruz José⁶⁷⁸,Lara-Ceniceros Tania E.⁶⁷⁸,Flores-Guerrero Mildred⁶⁷⁸,Saldivar-Guerra Enrique⁹¹⁰⁸

Affiliation:

1. Lab. de Polímeros

2. Centro de Química

3. Instituto de Ciencias

4. Benemérita Universidad Autónoma de Puebla

5. C.P. 72570 Puebla

6. Cento de Investigación en Materiales Avanzados S.C. (CIMAV-Unidad Monterrey)

7. C.P. 66600 Apodaca

8. Mexico

9. Centro de Investigación en Química Aplicada

10. C.P. 25294 Saltillo

Abstract

We report the results from the reactions of 1-phenylethanol, 2-methylpropanol, trimethylsilanol and triphenylsilanol with TEMPO, OH-TEMPO and Br-TEMPO salt at different reaction conditions to obtain model functionalized compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA10056A

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